Assuming you're asking about
int *f; *f = 2;
The statement,
*f = 2;
says "dereference f to get a location; set the contents of that location to 2". "Set f to the location of 2" would be spelled
f = &2;
This is partly a matter of the difference between assignment and definition(/equality).
The first of these is invalid C (undefined behavior) because it uses a value (the contents of f) before initialization.
The second is invalid C (compile error) because 2 is not an l-value (that is, it does not have a location).
Edited to add: I will note that I don't think there is any reason
*f = 2;
couldn't mean to give f the addess of 2, as by analogy to structural pattern matching, but that the syntax is already taken for something else.