To the first, yes. For example
http://en.wikipedia.org/wiki/Lema%C3%AEtre_coordinates is one.
To the second, when we talk about "coordinates" in GR, we're talking about parametrizing a volume of space-time. Given one parametrization, it is possible to create another parametrization that blows up at any particular spot - not because space-time is weird there - but because you picked a bad coordinate system.
The existence of parametrizations that carry through the event horizon demonstrate that the singularity at the event horizon in Schwarzschild's original metric is not a real problem for GR.
However the singularity at the middle of the black hole is a spot where GR breaks down. It is widely believed that a theory that combines GR and QM will make that singularity impossible.