If someone really needs those skills to do the job, then perhaps you can transform a negative into a positive: "New hire will receive on-the-job training time and budget in Mongo, Python, and Hadoop." That would attract a lot of people! And probably adding training is cheaper than raising the salary.
Once your ad has a clear message, perhaps you can use it in more targeted venues than SO. Imagine a CS student at Dublin University seeing a flier on their department bulletin board:
Junior C# Developer Wanted
Excellent Salary
Will Train in Python, Mongo, Hadoop
That's something you might even be able to send to a couple professors and ask if they could pass it on to any outstanding seniors.Even better would be to s/Excellent Salary/€35 - 45k/.