A VC invests $10MM at a $100MM valuation and owns 10% of the company with preferred shares. For simplicity, we'll assume they are the only holders of preferred shares.
An employee is given $500,000 in common stock, equal to 0.5% of the company at the same $100MM valuation.
The company then sells itself to an acquirer for $11MM, substantially below the $100MM valuation. The VC, with preferred shares, gets paid first. So they get their $10MM back. The remaining $1MM would then be divided among common stock holders. The employee above would get $5,000, instead of the $55,000 that 0.5% of $11MM would imply.
In the real world, founders, executives, and VCs often get preferred shares, which ultimately screws regular employees.