I frequently rank Microsoft's product line as follows:
1 - Natural keyboard - the one there is no reasonable replacement for (the kinesis keyboards are 5 times as expensive). If there is a reason my none of my machines is 100% Microsoft free, this is it.
2 - their mice - simple, precise, comfortable, inexpensive
3 - SQL Server - it almost makes having a Windows server around worth the pain.
Having said that, I have enormous respect for PostgreSQL. It's a very solid RDBMS and it's my database of choice most of the time. It is more comfortable to use from a command line than SQL Server will ever be (which is OK, because a CLI is not a high priority over there).