Despite geostationary satellites operating in an environment that's nominally -265 or so degrees celcius, the problem they usually experience is overheating, not freezing. Blackbody radiation will eventually carry the heat away, but we're talking decades to get to -100 or so.
For instance, a human body at rest generates about 150 watts of power, which would kill you in geostationary orbit without a cooling system. It would kill you because it wouldn't take long for your body temperature to rise to 52 degrees, at which point your cell metabolism abruptly stops (your mitochondria will stop generating energy). It would take longer than it takes you to choke though. Though nobody's ever tried for obvious reasons, you should be able to exit a space station and get back in with just a helmet that protects your mouth and nose and ears from decompression. You wouldn't freeze, you wouldn't explode. You'd overheat in 10-15 minutes or so. If you survive that, you'd die 2 weeks later from radiation poisoning. On the moon you need heating, because it actually has an atmosphere that would carry heat away.
It is fun reminiscing about just how special our place in the universe is. Human bodies wouldn't be able to survive on planets 30% closer to the Sun, or about 15% farther away. We wouldn't be alive without a mostly oxygen atmosphere, because without the ozone layer, solar radiation would kill us. Without the earth magnetic field, solar radiation would kill us. Without the sun protecting us from interstellar radiation, we'd die. If our solar system was further to the outside of the milky way, we wouldn't survive the radiation, solar protection or not. If it was closer to the middle, we wouldn't survive. It's unknown whether it's a black hole at the center or something else, but it sure outputs a lot of radiation. Oh, and we're in the < 0.1% of the milky way that hasn't experienced a supernova explosion for about 3 billion years (a supernova explosion at 20 lightyears or less would kill all life on earth. 50 lightyears is considered the minimum safe distance for large mammals to survive). The milky way has collided with at least 3 other (tiny) galaxies, none of the collissions were (are) anywhere near us, as the tidal stresses would alter planetary orbits, and so on and so forth.
All of this is ignoring the physical necessities for life to exist. If the fine structure constant, for instance, was 0.1% bigger or smaller, there would be no chemistry, and no humans. If the speed of light was ~5% bigger or smaller, there would be no atoms, as there would not be any stable electron orbitals, and so on.