The DC damage is a condition called 'muscular tetanus'. The main risk with AC at medium voltages (say 40 to 250 V) is that your heart goes haywire. Though those voltages could easily kill you too.
Yes, you should always be careful. But DC is most definitely more dangerous at the same voltage once you get over 48 V DC (the so called 'safe voltage', but that's a misnomer because under the wrong conditions voltages lower than that can still be fatal). The critical component by the way is current not voltage. Voltage really doesn't kill but current will. AC voltages are typically reported RMS, whereas with DC the 'peak' is also the average. Assuming the DC supply can produce as much current as the AC supply.
Being shocked by neither is good. But the choice between 200V DC and 200V AC is a fairly easy one for me and I've been shocked multiple times by both during my very long time of taking stuff apart and fixing things (yes, I try very hard to avoid that). The AC ones were mostly non-events, the DC ones were (even at lower currents) things to remember years later. Quite possibly that's not correlated with safety but it is definitely a data point (or rather several of them). Avoiding being shocked is a very good way of never having to find out how accurate this all is. One particularly memorable incident was hooking myself accidentally to the HV supply of an old tube radio. Don't do that. And be extremely careful with capacitors and DC batteries, they can supply a ton of current long enough to kill you. HV transformers much less so. (At least, the ones that you would normally encounter outside of industrial gear). And I suspect that the internal resistance of those supplies has a lot to do with whether you're going to be dead or writing about your experiences because it has a very direct impact you the current resulting. HV AC supplies that will supply very high current are hard to find, usually are transformers with relatively thin secondary windings. A battery pack like this is made to supply 100's of Amps at 100's of volts. That's lethal, make no mistake about that.
That battery bank cost $7200, 2005 or so prices.
More than you ever wanted to know: