The diversification buys me reduced risk of concentrated failure, I would assume just the same in philanthropy. If I give 100% of my donation to one organization, and it turns out they "perform" worse than I expected, it may have been better to split my donation among multiple organizations all of whom I expect to be highly efficient but cannot necessarily predict. Particularly in cases of multi-millions or billions when, even split, the money will meet a minimum threshold to make a difference.