Consider a population where 99% of users use IE, and 1% of users use Chrome.
From that population you can draw a biased sample consisting of the 99% IE users and conclude that there are no Chrome users at all.
Or you could draw a random sample of 1% of the population, and assuming that 1% adds up to enough people, your chances of drawing a random sample that did not include a reasonable number of Chrome users too would be extremely low.
So depending on methods used, even a 99% sample may be entirely meaningless when compared to a 1% sample.