May I ask why?
I see why maybe using your own compiled 2.7 or 3 might be nice, I don't, I just use the one that comes in with CentOS/RHEL 6.
* It get regular security updates from upstream
* Easy to install, it is part of existing package dependency chain (as opposed to say doing make ; make install from source)
* It comes with a default repo
* Most Python packages today are compatible with 2.6