If you do happen to be doing something where the difference is truly going to matter, or you're writing a library anticipating needing that kind of performance, using mutability internally in your functions isn't discouraged as long as they remain referentially transparent: http://clojure.org/transients
Likewise mutable data structures while not the default, can be implemented in Haskell, they just have some caveats attached and shouldn't be used lightly. In other words, all things being equal, use the immutable data structure, but if you have a good reason to, you can use a mutable data structure instead, just be sure you know what you're getting into.
I was a bit confused because O(log_32(n)) = O(log(n)) = log(32)+log(n) = O(log(32n)), so no matter how I parsed it I would just get O(log(n)) :)