If you're asking interview questions that can be googled in 20-30 seconds, you're wasting your time and theirs.
An interview should be the same as a discussion about concepts you'd have with a colleague. Does the person know the concepts? That's all that matters.
http://slady.net/java/bt/view.php?w=800&h=600 http://en.wikipedia.org/wiki/B-tree http://en.wikipedia.org/wiki/B%2B_tree http://guide.couchdb.org/draft/btree.html
Now if you make understanding B-trees a prerequisite for the job, I can at least learn it ahead of time for the position.
What about just some things. And in most cases, it's not learning for the first time but brushing up on the topic. To expect people to have encyclopedic knowledge of every edge-case problem your company deals with on a day-to-day basis is ridiculous.
There's a difference between things you know you don't know (and therefore can google), and things you don't know you don't know (and therefore will not google).
Imagine you hired some Cobol developers some decades ago, and therefore you would still be stuck using Cobol on your projects.
How does one become an experienced Pascal developer? That's somebody else's problem.
You can require knowledge without using dealbreakers like "you must know b-trees". A better alternative would be to say "you need to know 30% of the following group of things: b-trees, tcp/ip vs udp, ..." and so on.
I don't mean to imply that this wouldn't be acceptable to you. I do "know" that I've been screened out after giving an answer like this (to the extent that I can really know the reason, legally they aren't allowed to say).