The one habit I think still needs to be taught to people on dating sites is the value of publicness and openness. About two years ago I got my mom to sign up for OkCupid (a few years after her divorce) and the biggest problem I encountered was her reluctance to be open. People are afraid to put any identifying information or any information that deviates from the public image they maintain at work and in social circles. This basically sets themselves up for failure because connecting with the right people for you really is dependent on both parties being open enough to find real connections. Jeff Jarvis I think has given one of the best talks on the value of openness. If you've never seen it, definitely check it out.
[0] http://buzzmachine.com/2010/04/22/privacy-publicness-penises...