Why not? I'm serious here, if you're serving thousands of clients in a web app, why wouldn't you want parallelism? I mean, sure at small loads you don't need it, but what about scaling up?
Also, I find using compojure for web app development to be an absolute dream. I might need to get out more (my day job is java web apps), but I love the ability to iterate rapidly in the repl on a web app without having to restart my JVM.