As a thought experiment, imagine Google asking Peter Norvig to document everything he knows. The key assumption here is that what really makes your key employees valuable is documentable, and transferable (from said document to someone else's head) to the point where someone else can just read some document and replace him.
Sure, documenting some things may be valuable, but 'fire your most valuable team member' is either utter cluelessness,or just link bait.