Never mind that the Starlink radio arrays are, well, radio arrays that quite effectively cover the whole planet. If you think of each satellite as a radio telescope, its resolution is crap and probably cannot disambiguate a carrier group from anything else (at least according to disclosed specs). But it would be quite interesting to build a synthetic aperture array out of multiple satellites. This would rely on emissions from the ships themselves, but I bet it could be done and could locate ships quite nicely.