I have, you're pushing nonsense.
The methanol doesn't "come out in the heads" and batch size doesn't affect the final concentration as a % because roughly the same ratio is present during a run with a slight in crease in the tails due to the with methanol bonds with water.
https://op.europa.eu/en/publication-detail/-/publication/0b9...
https://www.sciencedirect.com/science/article/pii/S240584402...
Methanol poisoning comes from tainted consumables.