I did my own testing where Brotli also ended up better than ZSTD: https://news.ycombinator.com/item?id=46722044
Results by compression type across 55 PDFs:
+------+------+-----+------+--------+
| none | zstd | xz | gzip | brotli |
+------|------|-----|------|--------|
| 47M | 45M | 39M | 38M | 37M |
+------+------+-----+------+--------+