The only place PFAS is used in an FDM printer is the filament guide some printers have. That's a Teflon tube that the filament travels in towards the hotend.
Bowden style printers tend to have a long tube, direct drive printers sometimes have a short tube fully contained in the hotend assembly.
I don't see how PFAS can be used as a filament in FDM printer. It's not a thermoplastic, that's one of its advantages as a material.