Personally, as a DM of casual games with friends, 90% of the fun for me is the act of communal storytelling. That fun is that both me and my players come to the table with their own ideas for their character and the world, and we all flesh out the story at the table.
If I found out a player had come to the table with an LLM generated character, I would feel a pretty big betrayal of trust. It doesn't matter to me how "good" or "polished" their ideas are, what matters is that they are their own.
Similarly, I would be betraying my players by using an LLM to generate content for our shared game. I'm not just an officiant of rules, I'm participating in shared storytelling.
I'm sure there are people who play DnD for reasons other than storytelling, and I'm totally fine with that. But for storytelling in particular, I think LLM content is a terrible idea.