Moving the monochromatic BT.2020 colors from 630 nm, 532 nm and 467 nm could get a little increase in color space coverage, but at the expense of a lower efficiency in power consumption to brightness conversion. 467 nm is not a very pure blue, but the sensitivity of the eye drops very quickly in the blue region, so a better blue would require much more power. Similarly, though not so pronounced, for a different green.
Moreover, in the green region there is a gap, both for lasers and for LEDs, where the available devices have low efficiencies for converting electrical power to light, so changing the frequency of the primary green color would have to take that into account too.
In conclusion, I believe that the BT.2020 (actually BT.2100) color space is close to the best that can be done in displays of reasonable price and energy efficiency.
A true coverage of 100% of the BT.2100 color space can be realized only with laser projectors. Any display with LEDs or quantum dots will never have really monochromatic primary colors, though a coverage of significantly more than 90% of the BT.2100 color space is not too difficult. However, the advertised percentage of the color space may be misleading, because it varies depending on the kind of color space used for computations. A coverage percentage computed in OKlab would be more informative than a percentage computed in the XYZ color space.