>You mean, there should be a GUI
That must have been what Microsoft was figuring back in the 20th century.
Even in the latest W11, it's the same basic everyday GUI as in Windows XP :)
Just a little more intuitive now.
In XP from the Control Panel click System > Advanced > Environment Variables.
In Win11 from Settings click System > About > Advanced System Settings > Environment Variables.
Pay attention to your choice of User PATH, in addition to System PATH.
Make sure that things like %HOMEDRIVE% that you edit in, actually appear as "C:" once you are done editing, or you're not doing it ideally.