If there is not enough oxygen in the air to breathe, having more CO2 in the air will not save you.
Oxygen has to go above a certain partial pressure (happens at a couple meters down, I don't know the numbers of the top of my head) before it's toxic. And, carrying a tank that's got more than oxygen in it defeats the original military development and use model of rebreathers: no bubbles, and long submersion times.
The real problem for users is a lot of carbon dioxide scrubbing compounds will kill you if they get wet.
Engineering wise, I seem to recall pressure balancing (countering the water's pressure), and forcing your exhalation air through the scrubber being the complexity.
Theres a ton of complexity with rebreathers. And, thats before accounting for the fact they're mostly used in combat and cave diving. (Last I checked. Tbf, I got scared and changed career paths away from the sea after Rouge Waves became irrefutable fact)
If you go into an area with no oxygen, you will pass out very quickly with little warning except being dizzy, but you will not fail to feel like you need to breathe.
It might be slightly more safe to enter into a room full of co2 than a room full of nitrogen, because you might be alerted by the high co2 a few seconds before the dizziness takes over, but that doesn’t make rebreathers dangerous because you will forget to breathe. If you run out of oxygen, you’re unconscious in a few seconds anyway, co2 or no co2.