Haven't had that happen to me, but I did get asked by a clueless support rep from $VERY_BIG_MULTINATIONAL_CORPORATION whether I was also an employee due to their company name appearing in my email address. (Coincidentally I
used to consult for that company.) Long story short I set them straight rather than trying to parlay their ignorance to my advantage.
The most shocking thing was that I was calling them regarding an issue in which they required me to prove my identity, and yet the person I spoke with didn't seem to be well versed in security measures.
Also: I use a separate alias for every company (and sometimes individual) I deal with. In the 25 or so years I've been doing this, so far I'm up to over 1,000 aliases.