As far as I'm concerned, I think those things should be legal because not only sourcing them is easy anyway but it also escapes all quality control and regulation even though we still agree to sell much worse things as a society (like tobacco) and that's very incoherent.
I don't think any of the new age bullshit theory about healing mental illness (an already loosely defined thing) or whatever else is correct, but what is probably true, is that most of the stuff sold by the pharmaceutical companies is not any better (when it's not much worse) yet it is legal.
This is a classic case of capitalism bullshit: if you are having fun, you can't be a productive individual so that's not right, but in the meantime please buy our very similar drugs that's supposedly have the same results, without the fun.
One reason the advocates are going overboard with all the claims is probably because the industry is allowed to do the same with much less scrutiny, so it is an attempt at equilibrium, I guess. I doubt they will be successful at fighting fire with fire but it is annoying that it is such a political issue, people should be allowed to take those things if they want to...