Other order of magnitude indicators are capitalised to distinguish them from their smaller counterparts (millimetre/Megametre).
Wikipedia states that the distinction is because units named after a person always start with a capital letter. I've always assumed Hz has to be capitalised to prevent confusion with the hecto prefix (hHz being 100Hz). I don't think there's a unit or order of magnitude that's abbreviated to `z`, so in theory "Hz" could just be "H",
I think Hz is more readable, but that's probably because I'm used to it.