Off the top of my head: saving the NHS from decades of under-investment; introducing the National Minimum Wage; putting in place a huge school repair programme; ending the Troubles in NI; writing off the debts of poorer countries; Scottish devolution; and, for the majority of their term at least, fiscal stability and consistent economic growth.
The other side of the coin is, of course, the Iraq War. We needn't debate that, because we'll surely violently agree, but let's not pretend the Blair/Brown partnership didn't lead to many positive things for the UK. It did.