As for "can you order more if SiFive goes out of business": the detail here is going to be in all the other bits on the chip. Maybe they're free licensed, maybe they're not. You probably wouldn't get the GDSII that SiFive sent to the fab. You'd need to arrange another shuttle run. You might be too small for the fab to return your calls.
It's a pretty niche kind of manufacturing activity. Not many businesses really need a custom CPU.