Slavs have been discriminated against quite terribly over history.
‘White’ is just a category invented by Anglos and other Germanics (including Scandis, Franks, excluding Slavs and Jews) to lump together the ‘good sort’ of light skinned people away from dark skinned people and the ‘bad sort’ of light skinned people.
If you want to get deeper into ethnic speculation, I suspect it’s because Slavs have historically absorbed non-negligible amounts of ‘other’ groups such as Turkic, Iranic and Mongol; and this sets them apart from the more insulated Germanic groups who perhaps feel it makes them superior. Look at Nazi views on Aryanism and how Slavs were considered impure (funnily enough, except Bohemians, Croats and Ukrainians for political reasons… there was a war on)