Nickel hydrogen has incredible endurance, but the part that really struck home with me: they measure the state of charge with a pressure gauge.
> We take the battery, put it in an open fire, and watch it continue to heat up. What ends up happening is that the pressure above top charge will force the hydrogen back into water. And then we have a release valve designed into the unit so at a predesigned pressure and temperature that will release, and you’ll get a steam vent.”
But what about the hydrogen ? doesn’t that risk getting vented out with the steam ? into the barbecue ?
What’s the self discharge characteristics ?
Doesn’t it say the hydrogen is vented as H2O?
Pressure vessel scaling laws say that all cylinders have the same mass efficiency, and making long thin cylinders is easier than making short squat cylinders.
Or, to put it a different way, NiMH batteries require a large interior surface area, and so the square/cube law forces them to look longer and thinner as they get larger.
> Nickel-hydrogen batteries look and work unlike any other battery. They consist of a stack of electrodes inside a pressurized gas tank. The cathode is nickel hydroxide while the anode is hydrogen. When the battery is charging, a catalytic reaction generates hydrogen gas. During discharge, the hydrogen oxidizes and converts back to water.
We should soon see if this is a viable business then.
This implies a bulk cost of about $57/kWh which is slightly cheaper than present day LFP (the primary competitor for grid-scale battery storage). IMO, it needs to be no more expensive than LFP, because LFP cells can be spec'd for ~8 years and it's hard to get people to invest on timescales longer than ~10 years.
Or does it just require occasional recharging with water or H2, and if so, what is the value of "occasional"?
Generally you make a battery by combining cells - they have a 1-1.5V terminal voltage. The image lower down shows a rack of them in a warehouse. I suspect you'd stack them up to a few hundred volts and plug them into an inverter.
I wonder if they require the same balancing as more delicate chemistries.
1. No thermal runaway and "phenomenal overcharge, discharge and deep-cycle performance"
2. "Flexible charge and discharge rates"
3. "Vessels can discharge to 100%"
4. Specified charging rate of C/12-C/2 (i.e. can be charged at rates from 1/12 the capacity per hour to 1/2 the capacity per hour)
They do require usage of a tiered BMS though: https://enervenue.wpenginepowered.com/wp-content/uploads/202...
But, keep in mind that Undecided is overly optimistic about pretty much every emerging technology.
GP's question is "Will the H2 migrate through the pressure tank after such a long time?"