I don't think most Austrian econmists would self-identify as neoliberals. Politically they tend to be Libertarians (in the U.S.) or free market anarchists or minarchists (or I suppose laissez faire). Basically free-market instead of stat interventions. I belive most neoliberals quite readily accept state interventions, central banking etc.
The core tenent is that the free market is the best allocator of factors of production and entrepreneurial profit is the guiding factor. The state tends to interfere with this. It's best summarized in the socialist calculation debate.
However, there's also basically a split (mostly reconciled these days) betwen a more Hayekian wing which is more accepting of the mainstream (and could possibly self-identify as neoliberals) and the state in general and a wing that is more in the spirit of von Mises.
Disclaimer: just interested in the history of economics, not an economist.