Datomic already sort of does this :) You configure a storage backend (Datomic does not write to disk directly) which can be dynamodb, riak, or any JDBC database including postgres. You won't get readable data in PG though, as Datomic stores opaque compressed chunks in a key/value structure. The chunks are adressable via the small handful of built-in indexes that Datomic provides for querying, and the indexes are covering, i.e. data is duplicated for each index.
Because, for example, your application is not tied to the JVM? You are uncomfortable using closed source software for such a critical piece of infra? As far as I can tell they don't even have a searchable bug report database! I'd hate to be the one debugging an issue involving datomic.