The danger here is that when you explain something to someone, and they get it, you get a warm fuzzy rush of happy brain chemicals. You will feel well-disposed towards candidates who appreciate and enjoy taking the breadcrumbs you feed them. Candidates who didn't think your clever insights were as clever as all that, or who fail to respond to your tutelage and try to solve it their own way... you'll get a negative feeling towards them. They're not playing your game.
That's great if you're interviewing a student to figure out if they will enjoy learning from you, and you will enjoy teaching them!
But while teacher/learner relationships might be part of your relationship with colleagues at work, it seems an odd part of the relationship to compatibility filter in an interview.