Both of these statements are untrue.
>People don't generally paint in photoshop
EVERYONE uses photoshop in the painting/art world. Seriously, almost everyone. It's the best app for it, and the only reason people use others in my experience is because they're either free or a one-time payment. Or, because they're painting on a tablet, where (the full) photoshop isn't available.
>while ProCreate is about natural-looking brush painting
This is also not true. People use procreate because of the simple UI, nice gestures, tailored to iPads, for a one-off payment - and because its simply just the best option available on iPads. There's no difference in what you can do with brushes, or "naturalness" between them. If anything, photoshop is better at natural-looking brush painting. If you're wanting natural looking brush painting, also check out the lesser-known Rebelle: https://www.escapemotions.com/products/rebelle/about?//produ... - which is designed to more simulate real physical paint, not just in terms of brush patterns but also mixing.