I still stand by my statement. Even at equilibrium it can lower in entropy. The equilibrium is simply the highest entropy state.
>I asked “How does your configuration where the balls were near one corner in the cube cause mercury to rise to a different level than the configuration where they occupy a larger volume near the center?” and the answer “The balls have to touch thermometer” doesn’t cut it. The balls don’t touch the thermometer in either case.
I stated this is pedantism. The concept and intuition remain true. I changed the definition so that it's a volume around the thermometer if the particle is in that volume and heading for the thermometer is counts as a collision.
I stated all of this already.
>You seemed to imply that the higher concentration means a different macrostate with lower entropy. Or maybe the low entropy in you example is because the balls are near a corner?
Yes. The higher concentration has a lower probability of occurring. And occupies a different temperature reading on the thermometer. Each temperature reading is a different macrostate.
>Anyway, it would indeed have been easier to say that definition of macrostate included the density of particles in each octant of the cube - or something like that.
Sure, Divide the box into a bunch of cubes. If 1 or more particles are in the cube then that cube represents 1, otherwise 0. Add those numbers up and that represents a macrostate.
The inuition remains the same. For all particles to be concentrated in 1 cube is a very low probability. And the macrostate will be quite low too. With enough cubes and boxes such a state has a very low probability of occuring.
But all of this is, again, independent of your knowledge of where the particles are in each cube.