You don't use email addresses at all with Pwned Passwords. The documentation says "first 5 characters of a SHA-1 password hash", not email-address hash.

HIBP does not have a way to search for which password hashes are associated with a given email address, as this would be far more useful to attackers than to victims. The only data that Pwned Passwords exposes is a list of password hashes and the number of times that hash was used. The expectation is that even if that leaked password was actually for someone else's account, you still shouldn't be using it.