Here's a simple analogy: you have a 2 foot kiddie pool in your back yard. The pressure is whatever pressure water is at under a depth of 2 feet. If you have 2 pools, one radius 5 feet and one radius 10 feet they're both at the same pressure. The depth of the water didn't change. Length of the wall doubled (circumference) but the area squared. This is why you can hold back a storm surge with sandbags. The fact that effectively infinite water is behind it doesn't matter.
If you have some gas stored at 100 psi, you need a wall thickness to withstand 100 psi. If you create a sphere with twice the radius you still need a wall thickness to withstand 100 psi. A bit more than that because the tank also needs to support itself, but that's minor relative to its contents. That's why methane storage tanks are big spheres, to minimize surface area: https://i0.wp.com/tmicoatings.com/wp-content/uploads/2019/09...
I'm not sure how applicable rocket motors are to this comparison (maybe you missed that they were talking about rocket motors?). Rocket motors have a big bell and throttle at the end, which is analogous to a big load. And the bigger the rocket combustor the more thrust it needs to support. This is a whole different kind of load, it's not a simple pressure vessel.
In particular:
> The pressure load trying to cause such a separation is proportional to the surface area of the slice.
This is probably taking into account something like greater fuel combustion. Because otherwise it's blatantly wrong. A tank at 100 psi still has 100 psi of pressure whether it's got a volume of 1 cubic meter or 10 cubic meters.