Nope, SMTP is the older one. RFC 821
standardized SMTP, RFC 760
created IPv4, and in fact if you read RFC 801 it required a switchover from the previous Network Control Protocol (NCP) to then-new TCP/IP on the start of 1983. As the grandparent points out:
> RFC numbering only indicates the order in which these protocols were standardized (or at least proposed for standardization), not when they were first used.
Even today, many things are de-facto implemented before standardized so I personally don't think that it's correct to look at the RFC date as the date to consider.