It may sound weird but it's not about the intuition but your guts which is, I know it's weird, different. It's "how you feel" and your mood is driven a lot by your guts. It's really something which is more about the body than the brain if you will.
And if you feel very good with someone, very very good, well you either have your cofounder/spouse in front of you or a psychopath/charmer/salesman (because this is what they do, they hack your guts). I'm serious. It goes like this: you dont feel particularly good, pass, you feel good, psycho or spouse?.