Not in comparison to Perl, which usually has multiple ways to do anything, each 'obvious' to different sets of people (each Perl codebase therefore seems to have a distinct dialect based on which 'obvious' alternatives are chosen).

The other direction languages can take that is being contrasted, is there being one non-obvious way to do something.

Python's 'most obvious way' isn't necessarily the fastest/most concise/most efficient/scalable/etc. way to do something in Python, but it will usually be obvious to most Python developers. And although broad styles have certainly developed over time (imperative, functional, OO) as Python has gained power and flexibility, the dictum still largely holds true.