Personally I'd be very wary of Lithium as the code looks pretty slipshod internally from a brief scan into it, but Solar and FLOW3 are solid projects.
Didn't dwell too much into Lithium's code but saw they have some interesting ideas also based on 5.3 features, e.g. they use a sort of aspect-oriented programming based on closures and lambdas. Sounds cool, even if only for experimenting with different programming approaches.
Symfony2, on the other hand, puts a fairly strong emphasis on security, is fully based around PHP 5.3 idioms, and is written with sparkling code.
[1] - http://dev.kohanaframework.org/issues/2766 comes immediately to mind; forget the resolution of the bug (such as it wasn't), the behavior of the developers is not good. I get the feeling from those who've used Kohana that this isn't a unique situation.