Whats inherently power of two about them?
I have two PS/2 era drives that predate your "rebranding". One, 20MB (actual 21.3MB or 20.3MiB) has a CHS geometry 612x4x17. The other, 40MB (41.5MB or 39.5MiB) has a CHS geometry of 1038x2x39.
None of these values are powers of two (other than heads, because platters happen to have two sides)
I'd argue that all we're seeing here is the long, long tail of lazy shortcuts taken in the early-home-computer era. Not a truth, a lazy shortcut - that software took as convention and hardware didn't.