The difference will not be audible to most people because of the equipment and environment. Besides, audio has been mastered for 128kbps MP3, which most people prefer. So unless they are going to change the mastering, this is double worthless.
But I’m not in the habit of telling people how to spend their money. If they enjoy the music more because they paid more for it, no objections here. I’ve got plenty of wasteful hobbies myself.