I would again emphasize that encoding/xml, to my knowledge, only has problems with this particular roundtripping use case. It can consume non-namespaced XML correctly, and handle namespaced XML as long as you don't plan on re-emitting XML.
What would probably end up happening is a new package appearing on github.com for this use case, forked off of encoding/xml, for this use case. (If you're looking for a project that might attain some use, this is a likely candidate.) Unlike something like Python where the core packages are often C-based and thus you can expect better performance from the built-in "set" than somebody's pure-Python "set" implementation from before the built-in, encoding/xml is just a pile of pure Go code whose only advantage is that it ships with the compiler. Anyone can replace it without incurring any other disadvantage whenever they like.
(I looked a few versions ago, FWIW; encoding/xml has deviated so much from what I forked that my fork is essentially dead and no longer releasable without basically starting over from scratch. Plus I built it with the idea that it should be a minimal modification (so I could port it forward, which turned out to not work, but it's still how it was built)... if I was truly forking I'd have done some more extensive changes to it to support namespaces in general, rather than for my particular case.)
Anyhow, upshot, the Go project as a whole is not stuck... it is specifically encoding/xml as the standard, built-in library that is stuck. It's not like Go is completely incapable of handling XML correctly from first principles for some reason or anything.