I think that's what he's talking about.
He's basically saying he doesn't believe the die is fair/unweighted.
So stating the odds of a fair die is kind of immaterial to his point. We need to demonstrate to the guy that the die is fair.
Someone else posted a link (I think) of 538 going over on how accurate they were. Whether their odds bore out. Here it is: https://projects.fivethirtyeight.com/checking-our-work/
Basically what they did was bucket every prediction by odds. If they predicted 70/30, it went in that bucket. And they're "right" at about the rate of their predictions. In other words, for every 70/30 prediction they made, the people/teams with 70% chance to win, won about 70% of the time.
That shows that 538 in this case is pretty decent at calculating odds.
Grandposter doesn't believe the die is fair. That's a different argument than the guy I responded to made.