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But to simplify, you don’t just release a gas on it’s own you need a dispersal system like an explosive.
The most recent example is https://en.wikipedia.org/wiki/Ghouta_chemical_attack which killed or incapacitated ~5,000 with a few rockets. It also acted at least in the short term as area denial which can be extremely useful.
PS: In terms of fighting a near parity army, simply using tents separated by sandbag walls makes bombs or rocket strikes significantly less effective. Add even the threat of chemical weapons and things become significantly more difficult. http://armymomstrong.com/wp-content/uploads/2010/02/2-milita...