> In the real number field, additive inverse of a positive real number is indeed the negative of that number. The negative of that number is also obtained by the application of unary negation operator on the positive number.

This is a fact that follows from the definition of +. But + needs to be defined before you can start making assumptions about what the additive inverse is. The set over which the field is defined (Z or R) already contains -3, -2 etc. and -3 * -2 or -3 + -2 needs to be defined when you're constructing the field. It then turns out that -3 is the additive inverse of 3. You can't use this when arguing about the definition of why applying * on negative 2 and negative 3 gives you the result positive 6. Because you need to define * over all members of the field before you construct a field in the first place.