I'll prioritize the 0.005L per 100km car for sure. That means the car can be driven for all its expected lifetime (500k km) in a single tank of gas, filled up at the time of purchase! That means there is a huge opportunity to further optimize for many things in the system:
- The car no longer needs to have a hole on the side for filling up. A lot of pipes can be removed. Gas tank can be moved to a safer/closer location where it is used.
- The dashboard doesn't need a dedicated slot for showing the fuel gauge, more wirings and mechanical parts removed.
- No needs for huge exhaust and cooling systems, since the wasted energy is significantly reduce. No more pump, less vehicle weights...
Of course, that 0.005L car won't come earlier than a good electric car. However, if it's there, I'd totally prioritize it higher than other things you listed. I think people tend to underestimate how small efficiency improvements add up and enable exponential values to the system as a whole.