Consider that light emitted from the Sun will decay with the square of the distance – as it is irradiated in all directions. To Voyager, the Sun looks like an ordinary star – although one much brighter than the others. Not much energy can be harvested there.
Until recently, photovoltaics were useless as far away as Jupiter. Given the tech advancements, we can now use them there (and have). Farther than that and you are bumping into practical limits.