Simple things that people like reasoning about and visualizing with printf() statements can be done in a debugger more easily after using your brain and logic to think about what the issue might be. Think a value got assigned a value it should't have? You add log statements, rebuild, relink, reproduce; or, you could just set a hardware watchpoint to print the backtrace whenever it changes. In my experience people don't reach for the debugger way of doing it simply because it might not be needed all the time and the syntax is forgotten. Diving into `man` or docs is harder than printf(). Use those skills more regularly and/or make a cheatsheet, macros, etc. and it is less of a problem.
Debuggers must be used in certain situations. Personally, the canonical example I use is tracking down compiler bugs. I and colleagues have been hit with a number and it would be utterly hopeless to attempt to reason about what is going on without a debugger. (One particular past case that stands out was the compiler, under very certain circumstances, not restoring a register that it was obligated to restore when emitting a catch block. Isolating the root cause and generating a reduced example was loads of fun /s, would not recommend.) Then there's kernels, runtime engines with JIT, diagnosing unreproducible problems in situ where the executable can't be replaced or restarted, and the list goes on...